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| The vacuum UV photoabsorption spectrum of the geminal dichloroethylene (1,1-C2H2Cl2) in the 5–20 eV range. A vibrational analysis of the valence and Rydberg states Locht, R.; Dehareng, D.; Leyh, B. (2017). The vacuum UV photoabsorption spectrum of the geminal dichloroethylene (1,1-C2H2Cl2) in the 5–20 eV range. A vibrational analysis of the valence and Rydberg states. Journal of Physics Communications 1(4): 045013. https://hdl.handle.net/10.1088/2399-6528/aa93a3
In: Journal of Physics Communications. IOP Publishing: United Kingdom. e-ISSN 2399-6528
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2B1) ionic ground state. The vibrational structure analysis excitation leads to the following wavenumbers: ω2 ≈ 1310 cm−1 (162 meV), ω4 ≈ 650 cm−1 (81 meV) and ω5 ≈ 290 cm−1 (37 meV). These modes can be assigned to the C=C stretching, to the symmetric C–Cl stretching and to the symmetric Cl–C–Cl bending vibrations respectively. By the same way, eight other Rydberg states were analyzed. For the first time the vacuum UV spectrum of 1,1-C2H2Cl2 has been recorded in the 10–20 eV range, revealing intense broad bands which are assigned to transitions to Rydberg states converging to excited states of 1,1-C2H2Cl2+. Assignments are also proposed for the vibrational excitations observed in this range. |
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2B1) ionic ground state. The vibrational structure analysis excitation leads to the following wavenumbers: ω2 ≈ 1310 cm−1 (162 meV), ω4 ≈ 650 cm−1 (81 meV) and ω5 ≈ 290 cm−1 (37 meV). These modes can be assigned to the C=C stretching, to the symmetric C–Cl stretching and to the symmetric Cl–C–Cl bending vibrations respectively. By the same way, eight other Rydberg states were analyzed. For the first time the vacuum UV spectrum of 1,1-C2H2Cl2 has been recorded in the 10–20 eV range, revealing intense broad bands which are assigned to transitions to Rydberg states converging to excited states of 1,1-C2H2Cl2+. Assignments are also proposed for the vibrational excitations observed in this range.